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Milk

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Physical and chemical structure

Milk is an emulsion of butterfat globules within a water-based fluid. Each fat globule is surrounded by a membrane consisting of phospholipids and proteins; these emulsifiers keep the individual globules from joining together into noticeable grains of butterfat and also protect the globules from the fat-digesting activity of enzymes found in the fluid portion of the milk. In unhomogenized cow's milk, the fat globules average about four micrometers across. The fat-soluble vitamins A, D, E, and K are found within the milkfat portion of the milk (McGee 18).

The largest structures in the fluid portion of the milk are casein protein micelles: aggregates of several thousand protein molecules, bonded with the help of nanometer-scale particles of calcium phosphate. Each micelle is roughly spherical and about a tenth of a micrometer across. There are four different types of casein proteins, and collectively they make up around 80 percent of the protein in milk, by weight. Most of the casein proteins are bound into the micelles. There are several competing theories regarding the precise structure of the micelles, but they share one important feature: the outermost layer consists of strands of one type of protein, kappa-casein, reaching out from the body of the micelle into the surrounding fluid. These Kappa-casein molecules all have a negative electrical charge and therefore repel each other, keeping the micelles separated under normal conditions and in a stable colloidal suspension in the water-based surrounding fluid^[3] (McGee 19–20).

Both the fat globules and the smaller casein micelles, which are just large enough to deflect light, contribute to the opaque white color of milk. The fat globules contain some yellow-orange carotene, enough in some breeds — Guernsey and Jersey cows, for instance — to impart a golden or "creamy" hue to a glass of milk. The riboflavin in the whey portion of milk has a greenish color, which can sometimes be discerned in skim milk or whey products (McGee 17). Fat-free skim milk has only the casein micelles to scatter light, and they tend to scatter shorter-wavelength blue light more than they do red, giving skim milk a bluish tint.^[4]

A simplified representation of a lactose molecule being broken down into glucose and galactose.

Milk contains dozens of other types of proteins besides the caseins. They are more water-soluble than the caseins and do not form larger structures. Because these proteins remain suspended in the whey left behind when the caseins coagulate into curds, they are collectively known as whey proteins. Whey proteins make up around twenty percent of the protein in milk, by weight. Lactoglobulin is the most common whey protein by a large margin (McGee 20–21).

The carbohydrate lactose gives milk its sweet taste and contributes about 40% of whole cow milk's calories. Lactose is a composite of two simple sugars, glucose and galactose. In nature, lactose is found only in milk and a small number of plants (McGee 17). Other components found in raw cow milk are living white blood cells, mammary-gland cells, various bacteria, and a large number of active enzymes (McGee 16).

Processing

In most Western countries, a centralised dairy facility processes milk and products obtained from milk (dairy products), such as cream, butter, and cheese. In the United States, these dairies are usually local companies, while in the southern hemisphere facilities may be run by very large nationwide or trans-national corporations (such as Fonterra).

Pasteurization and raw milk

Pasteurization kills many harmful micro organisms by heating the milk for a short time and then cooling it for storage and transportation. Pasteurized milk is still perishable and must be stored cold by both suppliers and consumers. Dairies print expiration dates on each container, after which stores will remove any unsold milk from their shelves. In many countries it is illegal to sell milk that is not pasteurized.

Milk may also be further heated to extend its shelf life through ultra-high temperature treatment (UHT), which allows it to be stored unrefrigerated, or even longer lasting sterilization.

Those preferring raw milk argue that the pasteurization process also kills beneficial microorganisms and important nutritional constituents. The resulting pasteurized product is said to contribute to its own indigestibility, be less nutritious, and turn rancid (as opposed to sour) with age. However, unpasteurized milk can harbor harmful disease-causing bacteria such as tuberculosis, brucellosis, salmonella, diphtheria, polio, and escherichia coli.^[5] The cows must be maintained in very sanitary conditions and a watchful eye kept as to disease testing and vaccinations for this to be completely safe. Cheeses made with raw milk are regarded as safer as the milk typically had to be heated to some extent anyway to make the cheese, and this would kill many of the dangerous organisms possibly present.

Creaming and homogenization

Upon standing for 12 to 24 hours, fresh milk has a tendency to separate into a high-fat cream layer on top of a larger, low-fat milk layer. The cream is often sold as a separate product with its own uses; today the separation of the cream from the milk is usually accomplished rapidly in centrifugal cream separators. The fat globules rise to the top of a container of milk because fat is less dense than water. The smaller the globules, the more other molecular-level forces prevent this from happening. In fact, the cream rises in cow milk much quicker than a simple model would predict: rather than isolated globules, the fat in the milk tends to form into clusters containing about a million globules, held together by a number of minor whey proteins (McGee 19). These clusters rise faster than individual globules can. The fat globules in milk from goats, sheep, and water buffalo do not form clusters as readily and are smaller to begin with; cream is very slow to separate from these milks (McGee 19).

Milk is often homogenized, a treatment which prevents a cream layer from separating out of the milk. The milk is pumped at high pressures through very narrow tubes, breaking up the fat globules through turbulence and cavitation.^[6] A greater number of smaller particles possess more total surface area than a smaller number of larger ones, and the original fat globule membranes cannot completely cover them. Casein micelles are attracted to the newly-exposed fat surfaces; nearly one-third of the micelles in the milk end up participating in this new membrane structure. The casein weighs down the globules and interferes with the clustering that accelerated separation. The exposed fat globules are briefly vulnerable to certain enzymes present in milk, which could break down the fats and produce rancid flavors. To prevent this, the enzymes are inactivated by pasteurizing the milk immediately before or during homogenization. Homogenized milk tastes blander but feels creamier in the mouth than unhomogenized; it is whiter and more resistant to developing off flavors (McGee 23). Creamline, or cream-top, milk is unhomogenized; it may or may not have been pasteurized. Some have suggested that homogenized milk is harder to digest or not as suited to some people as is unhomogenized, it was just for convenience so one didn't have to shake the bottle, and isn't as important as is pasteurization which is done for safety purposes.

Unhomogenized has made a small comeback in a few areas, such as the west coast of the United States where Srauss Family Creameries, based originally out of Sonoma, sells one line of organic milk with the cream still on top in old-fashioned glass bottles. They still however pasteurize it to prevent harmful microorganisms.

Additives & Flavored Milk Drinks

Milk, sold commercially in countries where the cattle (and often the people) live indoors, commonly has vitamin D added to it to make up for lack of exposure to UVB radiation. Milk often has flavoring added to it for better taste or as a means of improving sales. Chocolate flavored milk has been sold for many years and has been followed more recently by such other flavors as strawberry and banana.

South Australia has the highest consumption of flavoured milk per person in the world, where Farmers Union Iced Coffee outsells Coca-Cola, a success shared only by Inca Kola in Peru and Irn-Bru in Scotland.

Switzerland has a soft drink based on milk that tastes and looks much like SevenUp. This popular "milk-cola", named Rivella, is in fact the national soft drink and comes complete in low calorie & low sugar varieties even. To taste it one would not think at all that it is based from milk.